Using NMR, photochemistry, and a femptosecond laser setup, the lifetimes of radical species in solution can be determined. These data can be fitted to a diffusion model that includes a microscopic viscosity, or the solvent “cage-effect.”
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Using NMR, photochemistry, and a femptosecond laser setup, the lifetimes of radical species in solution can be determined. These data can be fitted to a diffusion model that includes a microscopic viscosity, or the solvent “cage-effect.”